September 24, 2024 by Chinese Academy of Sciences
Collected at: https://phys.org/news/2024-09-quantum-approach-captures-nanoscale-electrochemical.html
Battery performance is heavily influenced by the non-uniformity and failure of individual electrode particles. Understanding the reaction mechanisms and failure modes at nanoscale level is key to advancing battery technologies and extending their lifespan. However, capturing real-time electrochemical evolution at this scale remains challenging due to the limitations of existing sensing methods, which lack the necessary spatial resolution and sensitivity.
Now, researchers from Suo Liumin’s team and Liu Gangqin’s team from the Institute of Physics of the Chinese Academy of Science have developed a quantum sensing approach based on diamond nitrogen-vacancy (NV) centers.
The study, titled “Operando quantum sensing captures the nanoscale electrochemical evolution in battery,” was published in Device on September 10.
NV sensors offer spatial resolution from 1nm to 1μm and are sensitive to variations in temperature, stress, and magnetic fields, holding great potential for real-time, non-destructive monitoring of battery electrode particles.
Using an integrated device combining a quantum sensing system with a battery, researchers achieved in-situ monitoring of nanoscale active material particles, demonstrated by Fe3O4 electrodes.
Their findings revealed non-uniform phase transformations from Fe3O4 to FeO and then to Fe during discharge, with significant microscopic kinetic differences across regions.
The study also uncovered superparamagnetic behavior in Fe particles.
The significant difference in magnetic field and temperature distribution within the electrode are also revealed through multithreaded sensing in this study.
Magnetic field mapping inside the Fe3O4 electrode. Credit: Institute of Physics
Diamond quantum sensors capture the nanoscale electrochemical evolution of the Fe3O4 electrode. Credit: Institute of Physics
These results demonstrated the potential of diamond NV centers for wide-area, high-resolution characterization of nanoscale region within an electrode, offering new insights into material behavior and failure mechanisms.
More information: Binghang Liu et al, Operando quantum sensing captures the nanoscale electrochemical evolution in batteries, Device (2024). DOI: 10.1016/j.device.2024.100521
Journal information: Device
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